pH Levels in Skincare: Why It Actually Matters

pH Levels in Skincare: Why It Actually Matters

Let’s cut to the chase—skincare is not just about throwing money at fancy serums and praying for miracles. If you’re using active ingredients, you need to get one thing straight: pH levels are a big deal. Ignore them, and you might as well be slathering overpriced goo on your face for fun.

What Even Is pH, and Why Should You Care?

pH (short for potential hydrogen, but don’t worry, there’s no test later) measures how acidic or alkaline something is on a scale from 0 to 14. Your skin naturally sits at a slightly acidic pH of around 4.7 to 5.5, which is its happy place. Mess with that balance, and chaos ensues—think irritation, breakouts, and a skin barrier that’s practically waving a white flag.

And if you’re using power players like Vitamin C, niacinamide, or hyaluronic acid, pH controls whether they actually do their job. Too high or too low, and you’re just rubbing in disappointment.

pH and Active Ingredients: The Balancing Act

Vitamin C: The Diva That Needs Everything Just Right

Vitamin C (specifically ascorbic acid) is notoriously high-maintenance. It works best at a pH below 3.5—any higher, and it oxidizes faster than an avocado left on the counter. And trust me, oxidized Vitamin C is not your friend. It loses potency and can even irritate your skin. Want to keep it fresh and effective? Vitamin C Oxidation: How to Store Serums Properly has the details.

Niacinamide: The Chill One (Most of the Time)

Niacinamide is like that easygoing friend who gets along with almost everyone. It thrives at a neutral to slightly acidic pH (5-6), meaning it plays well with most other ingredients. But mix it with a low-pH Vitamin C serum? Not the best idea. Some research suggests it can convert to niacin at lower pH levels, which can cause flushing and irritation. Not ideal. For a deep dive into how niacinamide interacts with other actives, check out The Science of Active Ingredients: Niacinamide, Vitamin C & Hyaluronic Acid.

Hyaluronic Acid: The Hydration Hero That Doesn’t Care About pH

Hyaluronic acid is refreshingly drama-free. As a humectant, it just wants to attract water and doesn’t care much about pH. But layering it after low-pH actives like Vitamin C or exfoliating acids? Genius move. It helps lock in hydration and supports your skin barrier—because trust me, you want that thing intact.

What Happens When You Ignore pH?

If you’re blindly slapping on products without thinking about pH, you might be wrecking your skin barrier without even realizing it. Signs of trouble? Tight, red, irritated skin that suddenly hates everything you put on it. A disrupted pH can lead to breakouts, dehydration, and even flare-ups of eczema or rosacea.

If your skin is screaming for help, focus on soothing ingredients that repair the damage. Need recommendations? Sensitive Skin SOS: Soothing Ingredients to Try has your back.

How to Use pH Knowledge to Your Advantage

  • Choose a Low-pH Cleanser – Harsh, alkaline cleansers (yes, that means bar soap) strip your skin’s natural acid mantle. Stick to pH-balanced options.
  • Layer Your Actives Like a Pro – Start with low-pH products (like Vitamin C or exfoliating acids), follow up with neutral pH products (niacinamide, peptides), and finish with your moisturizers.
  • Patch Test Like You Mean It – Just because a product has rave reviews doesn’t mean it won’t mess with your skin’s pH.
  • Avoid Mixing Clashing Actives – Vitamin C and niacinamide in the same routine? Risky. Low-pH exfoliants and retinol? A recipe for irritation.

The Bottom Line

Understanding pH isn’t just for chemistry nerds—it’s the key to making your skincare routine actually work. Whether you’re using Vitamin C, niacinamide, or hyaluronic acid, pH can be the difference between glowing skin and a compromised barrier. So check your labels, layer wisely, and keep your skin happy.

Abigail James profile picture

Abigail James

Learn More

As an author of two bestselling books and a global brand ambassador, I’ve shared my expertise and passion for skincare and wellness with the world. I also developed a groundbreaking holistic therapy called Rejuvology and now train other practitioners to become therapists of excellence.

Back to blog